#1
June 6th, 2016, 11:59 AM
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HCL SN1 or SN2
Hi I am interested in having the information about how the SN1/SN2) – The Nucleophile/Base react?
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#2
June 6th, 2016, 12:00 PM
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Re: HCL SN1 or SN2
the procedure of choosing if a response experiences SN1, SN2, E1, or E2 as soliciting an arrangement from inquiries so call it The Quick N' Dirty Guide To SN1/SN2/E1/E2. Once having taken a gander at a response and perceived that it has the potential for continuing through SN1/SN2/E1/E2 – that is, is it an alkyl halide, alkyl sulfonate (shortened as OTs or OMs) or liquor – and asked whether the carbon joined to the leaving gathering is essential, auxiliary, or tertiary, next can take a gander at the reagent for the response. In substitution responses, a nucleophile shapes another bond to carbon, and a bond between the carbon and the leaving gathering is broken. In disposal responses, a base structures another bond with a proton from the carbon, the C-H bond breaks, a C-C π bond shapes, and a bond amongst carbon and departing gathering is broken. In the event that you are asking, "Is the response: HCl + CH₃OH → CH₃Cl + H₂O a SN1 or a SN2process?". Provided that this is true, the answer is SN2. SN1 requires the development of CH₃⁺. This is a very shaky carbocation, so the response won't go SN1. The rate deciding stride in a SN2 response would be Cl⁻ + CH₃-O⁺H₂ → [Cl•••CH₃•••OH₂]⁺ → Cl-CH₃ + OH₂ This is the favored instrument on the grounds that: It dodges development of the methyl cation. There is no steric obstacle to posterior assault by a nucleophile. H₂O is a superb leaving bunch. Cl⁻ is a genuinely decent nucleophile. |
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