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3. Fastest distribution of some injectible material/medicine and with no risk of any kind can be achieved by injecting it into the
1) Muscles
2) Arteries
3) Veins
4) Lymph vessels

4. Which one of the following statements about the particular entity is true?
1) Centromere is found in animal cells, which produces aster during cell division
2) The gene for producing insulin is present in every body cell
3) Nucleosome is formed of nucleotides
4) DNA consists of a core of eight histones

91. Among the elements Ca, Mg, P and Cl, the order of increasing atomic radii is
1) Mg < Ca < Cl < P
2)
Cl < P < Mg < Ca
3) P < Cl < Ca < Mg
4) Ca < Mg < P < Cl


92. The reaction
2A(g) + B(g) Image not present 3C(g) + D(g)
is begun with the concentrations of A and B both at an initial value of 1.00 M. When equilibrium is reached, the concentration of D is measured and found to be 0.25 M. The value for the equilibrium constant for this reaction is given by the expression

1) [(0.75)3(0.25)] ÷ [(1.00)2(1.00)]
2)
[(0.75)3(0.25)] ÷ [(0.50)2(0.75)]
3) [(0.75)3(0.25)] ÷ [(0.50)2(0.25)]
4) [(0.75)3(0.25)] ÷ [(0.75)2(0.25)]


93.
Which of the following expressions correctly represents the equivalent conductance at infinite dilution of Al2(SO4)3. Given that Image not present and Image not present are the equivalent conductances at infinite dilution of the respective ions ?

1) Image not present
2)
Image not present
3) Image not present
4) Image not present


94.
The pressure exerted by 6.0 g of methane gas in a 0.03 m3 vessel at 129°C is (Atomic masses : C = 12.01, H = 1.01 and R = 8.314 JK-1 mol-1)

1) 215216 Pa
2) 13409 Pa
3)
41648 Pa
4) 31684 Pa

96. Among the following four compounds
a. Phenol
b. Methyl phenol
c. Metanitrophenol
d. Paranitrophenol
The acidity order is
1) d > c > a > b
2) c > d > a > b
3) a > d > c > b
4) b > a > c > d

97. Among the following which one has the highest cation to anion size ratio?
1) CsI
2) CsF
3) LiF
4) NaF
98. Three moles of an ideal gas expanded spontaneously into vacuum. The work done will be
1) Infinite
2) 3 Joules
3) 9 Joules
4) Zero

99. Which of the following species is not electrophilic in nature?
1) l

2) BH3
3) H3

4) O2


100. A 0.66 kg ball is moving with a speed of 100 m/s. The associated wavelength will be
(h = 6.6 × 10-34 Js)
1) 6.6 × 10-32 m
2) 6.6 × 10-34 m
3) 1.0 × 10-35 m
4) 1.0 × 10-32 m
Chemistry
101. Consider the following relations for emf of a electrochemical cell
(a) emf of cell = (Oxidation potential of anode) - (Reduction potential of cathode)
(b) emf of cell = (Oxidation potential of anode) + (Reduction potential of cathode)
(c) emf of cell = (Reductional potential of anode) + (Reduction potential of cathode)
(d) emf of cell = (Oxidation potential of anode) - (Oxidation potential of cathode)
Which of the above relations are correct?
1) (c) and (a)
2) (a) and (b)
3) (c) and (d)
4) (b) and (d)
102. In which of the following molecules the central atom does not have sp3 hybridization?
1) CH4
2) SF4
3) BF4-
4) NH4+

103. For vaporization of water at 1 atmospheric pressure, the values of ∆H and ∆S are 40.63 kJ mol-1 and 108.8 JK-1 mol-1, respectively. The temperature when Gibbs energy change (∆G) for this transformation will be zero, is
1) 273.4 K
2) 393.4 K
3) 373.4 K
4) 293.4 K

104. Match List-I (substances) with List-II (process) employed in the manufacture of the substances and select the correct option
List-I (substances) List-II (process)
A Sulphuric acid 1 Haber's Process
B Steel 2 Bessemer's Process
C Sodium hydroxide 3 Leblanc Process
D Ammonia 4 Contact Process

1) A-1 B-4 C-2 D-3
2) A-1 B-2 C-3 D-4
3) A-4 B-3 C-2 D-1
4) A-4 B-2 C-3 D-1

105. When glycerol is treated with excess of HI, it produces
1) 2-iodopropane
2) Allyl iodide
3) Propene
4) Glycerol triiodide

106. Some statements about heavy water are given below
1. Heavy water is used as a moderator in nuclear reactors
2. Heavy water is more associated than ordinary water
3. Heavy water is more effective solvent than ordinary water
Which of the above statements are correct?
1) 1 and 2
2) 1, 2 and 3
3) 2 and 3
4) 1 and 3

107. The compound A on heating gives a colourless gas and a residue that is dissolved in water to obtain B. Excess of CO2 is bubbled through aqueous solution of B, C is formed which is recovered in the solid form. Solid C on gentle heating gives back A. The compound is
1) CaCO3
2) Na2CO3
3) K2CO3
4) CaSO4 . 2H2O
Physics
71. The additional kinetic energy to be provided to a satellite of mass m revolving around a planet of mass M, to transfer it from a circular orbit of radius R1 to another of radius R2 (R2 > R1) is
1)

2)

3)

4)


72. The speed of a projectile at its maximum height is half of its initial speed. The angle of projection is
1) 60°
2) 15°
3) 30°
4) 45°

73. From a circular disc of radius R and mass 9M, a small disc of mass M and radius (R/3) is removed concentrically. The moment of inertia of the remaining disc about an axis perpendicular to the plane of the disc and passing through its centre is
1) (40/9) MR2
2) MR2
3) 4 MR2
4) (4/9) MR2

74. A particle moves in x-y plane according to rule x = a sin ωt and y = a cos ωt. The particle follows
1) An elliptical path
2) A circular path
3) A parabolic path
4) A straight line path inclined equally to x and y-axes

75. A closely wound solenoid of 2000 turns and area of cross-section 1.5 × 10-4 m2 carries a current of 2.0 A. It is suspended through its centre and perpendicular to its length, allowing it to turn in a horizontal plane in a uniform magnetic field 5 × 10-2 tesla making an angle of 30° with the axis of the solenoid. The torque on the solenoid will be
1) 3 × 10-3 N.m
2) 1.5 × 10-3 N.m
3) 1.5 × 10-2 N.m
4) 3 × 10-2 N.m