Can you please give here model question paper of Chemistry subject for Andra Prades Public Service Commission (APPSC) Degree Lecturers Exam ?

Hey , question paper of Chemistry subject for Andra Prades Public Service Commission (APPSC) Degree Lecturers Exam include questions from following topics of the Chemistry subject .

Syllabus for APPSC DL Chemistry subject Exam

Inorganic Chemistry:
1. Atomic structure & Chemical Bonding – Quantum theory Schrodinger – wave equation – Hydrogen
atom,Hydrogen molecule – Elements on valence bond – molecular orbital theories.
2. Determination of molecular structure – X – ray and electron diffraction methods.
3. Periodic classification (Classical and modern) periodic functions of elements – atomic volume – atomic
radious electronegativity-oxidation states – lattice energy and their applications.
4. Chemistry of d-block elements – Physical and chemical characteristics of the transition elements –
Characteristics related to electronic arrangements oxidation states – colow magnetic properties –
Complex formation – interstitial L-S couping – Hund’s rule. A General study of the first transition
series.
5. Chemistry of F-block elements – Lanthanons and Actinons – electronic configurations – oxidation’s
states – Separation of Lanthanons and Actinons.
6. Chemistry of complex compounds: Jourgenson and werner’s views – effective atomic number –
valence bond theory – Introductory treatment of crystalfield theory applied to complexes with coordination
number 6.
7. Isomerism in complexes: Geometrical and optical isomerism of four and six co-ordinated complexes.
Pearson’s theory of hard and soft acids and bases.
8. Study of the following elements and their modern Chemistry Be, Ti, Zr, Hf, V, Mo, W, U, and Th.
9. Alloys: Interimettalic compounds.

Physical Chemistry:
10. Radio activity: Elementary account of nuclear structure natural and artificial radio activity –
characterisation of relations – decay chains-half-life-decay constant and average life. Radio-active
series, atomic transmutation – atomic fission and fusion reactions and their applications – nuclear
isomers and their separations.
11. Kinetic theory of gases: Equations of state – critical constants – States of aggregation – liquid states –
viscocity – physical properties an chemical constitution – collision theory of derivation of the collision –
number from Kinetic theory of gases.
12. Chemical Kinetics: order and molecularity of reaction first order and second order reactions – law of
mass action – influence of temperature and pressure – thermo-dynamic derivation of Law of mass
action – unimolecular reactions Lindemann’s theory.
13. Thermodynamics: First law of thermodynamics and its applications to ideal gases, energy and
enthalpy changes in gases, heat capacities of gases and their inter-relation. Isothermal and adiabatic
processes – Kirchoff’s equation and its applications – Vant Hoff’s isotherm isochore equilibria in
heterogeneous system. Second Flaw of thermo dynamics (Joules and Joule Thomson experiments).
Entropy change in an isolated system for reversible and irrevbersible processes – Variation on entropy
of a system with temperature and pressure.

Organic Chemistry:
14. Heterocylic compounds and chemistry of nutral products – Importance of heterocyclic compounds –
classification based on the natury of heterocetom, size of the ring and II excessive and II deficient
nature of the ring.
A general and comparative study of Furan pyrole and thiophene Ring transformations. General
comparison with benzenoidd compounds, pyridine, quinotine, Isoquinoline and acrdine-fII deficient
nature of heterocylic rings – case of nucleophilic substitution.
15. Methods of synthesis, reactivity and properties of the following polynuclear aromatic compounds:
anthracene, Benzanthracene, Phenontherene Chryeneand picene.
16. Benzopyrones : Couamarins and Chromones.
17. Alkaloids: General occurrence, reactions and degradations. Chemical and Physico-Chemical methods
for the elucidation of structures-synthesis and structural elucidation of the following alakaloids –
atropine – cocaine - quinene – Narcotine – papaverine.
18. Organic reaction mechanism: Structure and reactivity of organic molecules – Factors affecting
Electron density in a band-inductive, induct rometric, mesomeric, (reasonance) and electrometric
effects, hyperconjugation – Dipole moments-acedic and basic strength of organic Compounds.
Modern concepts of organic reaction mechanisms – Addition, substitution and elimination reactions –
simple examples and their mechanism. The intermediate carboniumion formation and its participation
in organic reactions. Addition C-C, system-pinocol-pincolene rearrange rearrangements. Automatic
substitution – Formation and hydrolysis of esters.
19. Some name reactions: Wurtz-Friedel-Crafts, Fries-Gatter-mann – Perin – Beckmann’s rearrangements
and Grignard reactions.
20. Carbohydrates: General reactions of monosaccha rides – configurational studies on glucose, fructose,
sucrose, Recent advances in the Chemistry of cellulose and starch.
21. Proteins – Introduction to proteins – their classification – Nomenclature and distribution in nature
simple, amino acids – Isolation and their synthesis.
22. General Ideas regarding the chemistry of vitamins & Harmones nicotine, B-Carotene and Vitamin C.
23. Alicyclic compounds: Synthesis and reactions Bayers strain theory – Factors affecting stability of
conformation – terpenes – citral – gerniol – limonenene – terpinol – pinene and camphor.
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. Stereo Chemistry: Opticnal and geometrtic isomerism configuration of saturated molecues – DL and
RS configuration of optically active compound-racemic – mixtures – racemisation and resolution.
25. Molecular spectra: NMR, Chemical shift – Spin – Spincoupling – ESR of simple radicals – Rotational
Spectra, diatomic molecules, linear triatomic molecules, isotopic substitution – Vibrational and Raman
Spectra.

Physical Chemistry:
26. Electro-Chemistry: Equivalent conductance and its measurement. The independent migration of jons
– kholraush’s Law. Transport number and their determination. Ionic mobilities. Equivalent
conductance of weak and strong electrolytes. Inter-ionic attraction theory treated quantitatively-
Debye-huckle-onsager equation. Determination of solubilities from conductance measurements -–
Conductometric titration’s.
Ionic product of water and its determination from conductance and EMF methods – theories of acids
and bases – Hydrogen ion concentration and its measurements from E.M.F.measurements using
Hydrogen quin – hydroen and glass electrodes – Buffer solutions – Henderson’s equation
potentiometric titration’s – Determinations of equilibrium constant and solubilities from
E.M.F.measurements – Gibbs – Helmbholtz equation and its application to chemical cells.

27. Photo – Chemistry: Laws on absorption of light – Gretius – Draper Laws – Einstiens Law in Chain
reactions – Hydrogen chlorine reactions – absorption – Laws of absorption.
28. Surface Chemistry and catalysis – Absorption isotherms, surface area determination, heterogeneous
catalysis, acid-base and enzyme cotolysis.