I am searching here syllabus for MSC chemistry course offered by Pune University department of chemistry ?

Here I am giving you syllabus for MSC chemistry course offered by Pune University department of chemistry in a PDF file attached with it .

Semester – I
CH – 110 Physical Chemistry – I
CH – 130 Inorganic Chemistry – I
CH – 150 Organic reaction mechanism and stereochemistry.
CH – 107 Physical Chemistry practical ( Departmental Course)
CH – 127 Inorganic Chemistry Practical ( Departmental Course)

Semester – II
CH – 210 Physical Chemistry II
CH – 230 Inorganic Chemistry II
CH – 250 Synthetic organic Chemistry and Spectroscopy.
CH – 290 General Chemistry ( Departmental Course) elective)
CH – 247 Organic Chemistry practical ( Departmental Course)

Structure of
M.Sc. Part – II :- ORGANIC CHEMISTRY
SEMESTER : - III –
1. CH – 350 Organic Reaction Mechanism
2. CH – 351 Spectroscopic Methods in structure Determination
3. CH – 352 A Organic Stereochemistry.
B. Green Chemistry, Microwave reactions.
4. CH – 353 Pericyclic Reactions, Free radicals and Photo Chemistry.

SEMESTER :- IV –
1. CH – 450 Chemistry Of Natural Products.
2. CH – 451 Synthetic Methods in Organic Chemistry
3. CH – 452 Heterocyclic Chemistry; Chiron Approach; Medicinal
Chemistry;
Vitamins, Hormones Antibiotics etc.
4. CH – 453 Organic Molecules related to Nano matelial.
Practical Courses:-
1. CH – 347 Ternary Mixture Separation
2. CH – 447 Two Stage Preparations.
3. CH – 448 Project / Preparations

1) Recapitulation :-
Heat, Work, & Conservation of energy – The basic concepts, the first law,
infinitesimal changes, mechanical work, work of compression & expansion, free
expansion, Expansion against constant pressure, reversible expansion, Heat :- heat
capacity, enthalpy.
State functions & differentials – state functions, Exact & Inexact differential,
changes in internal energy, temperature dependence of the internal energy,
Temperature dependence of the enthalpy. Work of adiabatic expansion-
Irreversible adiabatic expansion, reversible adiabatic expansion.

2) The Second law of Thermodynamics
Measuring the dispersal the entropy, The second law, the definition of entropy,
the entropy changes in the system, natural events. Entropy changes in the universe
– The enthalpy change when a system is heated, Entropy changes in surroundings,
The entropy of phase transition, The entropy of irreversible changes.
Concentrating on the system – The Helmoltz & Gibbs function, some remarks on
the Helmholtz function, Maximum work, some remarks to Gibbs function 2.4
Evaluating the entropy & Gibbs function, The Third law of Thermodynamics,
Third law entropies standard molar Gibbs function.

3) Combining First & Second Law –
One way of developing the fundamental equations Properties of Gibbs
function, The temperature dependence of the Gibbs functions, The pressure
dependence of the Gibbs functions, The Chemical potential of a perfect gas, The
open system & changes of composition.

4) Changes of State :
Physical Transformation of pure materials. The stability of phases, Phase
equilibrium & phase diagrams, The solid – liquid boundary, The liquid-vapour
boundary, The solid- vapour boundary, The solid-liquid-vapour equilibrium.

5) Changes of State
Physical transformation of simple mixtures, Partial molar quantities Partial
molar volume, Partial molar Gibbs function, The thermodynamics of mixing – the
Gibbs function of mixing after thermodynamics mixing functions, The chemical
potential of liquid-liquid mixture, colligate properties- The common features, the
elevation of boiling point, The depression of freezing point, solubility, osmosis,
Mixtures of volatile liquid – vapour pressure diagram – The representation of
distillation, azeotropes, immiscible liquids.
6) Changes of States –
Chemical reactions, Which way is downhill – The Gibbs function minimum,
Exergonic & endergonic reaction, perfect gas equilibria, A recipe for equilibrium
constants real gas.

QUANTUM CHEMISTRY
Historical development of quantum theory principal of quantum mechanics,
wave particle duality, uncertainty principles, Schrödinger equation, operators simple
system – free particle, Particle in a box, Two dimensional Three dimensional box,
Hydrogen like atoms ( no derivation ) atomic orbital. Periods – 10
Reference Books -
1. Physical Chemistry - P.W. Atkin, ELBS fourth edition.
2. Physical Chemistry – R.A. Alberty, R.I. Bilby, Johy Wiley – 1995
3. Physical Chemistry – G.M. Barrow, Tata Mc – Graw Hill – 1988
4. Quantum Chemistry, - I . Levine, Fifth edition, Prentice Hall- 1999
5. Physical Chemistry – Thomas Engel, Philip Reid.

Section – II
1. CHEMICAL KINETICS
1. Recapitulation:-
Reaction rate, Rate law & rate constants, The determination of rate law, first
order reactions, second order reactions, Half life.

2. According for rate laws:-
Simple reactions, The temperature dependence of reaction rates, Reaction
approaching equilibrium consecutive reactions, The steady state approximations,
Pre-equilibira, Unimolecular reactions, Enzyme catalysis – Michaelis Menton
mechanism, Lineweaver and Eadie plots, The kinetics of complex reaction, Chain
reactions, the structure of chain reactions Explosions, - Fast reactions, flash
photolysis, Flow technique, relaxation methods,

3. Molecular reaction dynamics:-
Collision theory basic calculation, the steric requirement, Diffusion controlled
reactions- Classes of reactions, diffusion & reaction, the details of diffusion,
Activated complex. The reaction co – ordinate & transition state, the formulation
& decay of the activated complex, How to use the Eyring equation.
Thermodynamic aspect, reaction between ions, Dynamics of molecular collisions,

2. STATISTICAL THERMODYNAMICS
Thermodynamic probability of a system, the moat probable distribution, the
partition function, systems of independent particles, the energy of a system, the
separation of partition function, The partition function for translation, The
thermodynamic functions for translation, monochromic gases, Thermodynamic
function for rotation, vibration, & Electronic excitation, Rotation, the electronic
portion function, Results of statistical Calculation, statistical calculation of
equilibrium constant, entropy & probability, Bose-Einstein & Fermi Dirac Statistics.

Ref 1 Physical chemistry – P.W. Atkins, ELBS Fourth edition.
Ref 2 Principles of Physical chemistry – S.H. Maron & C.F. Pruton fourth edition
Ref. 3 Chemicals Kinetics, K.J. Laidler ( Tata Mc. Graw Hill) 1998
Ref . 4 Physical Chemistry, T. Engle and P. Reid, (Pearson Education) 2006
Ref. 5 Basic Chemical Thermodynamics, E. Brian Smith (ELBS) 1990
Ref. 6 Statistical Thermodynamics, L.K. Nash.
Ref.7 Physical Chemistry molecular approach, D.Mcquarie and J. Simom(Viva) 2000.


Contact details :
Department of Chemistry
University of Pune,
Ganeshkhind Road,
Pune - 411 007
Maharashtra State,
India.

Telephone
+91-020- 25696061
FAX
+91-020-25691728
E-MAIL
office@chem.unipune.ac.in

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