Can you provide me the Syllabus for M.Sc. Chemistry (CBCS) Programme offered by MLSU (Mohanlal Sukhadia University), Udaipur?

The Syllabus for M.Sc. Chemistry (CBCS) Programme offered by MLSU (Mohanlal Sukhadia University), Udaipur is as follows:


SEMESTER I

M1CHE 01-CT01: Inorganic Chemistry


UNIT-I
Stereochemistry and Bonding in Main Group Compounds, VSEPRT, Walsh diagrams (tri and
penta-atomic molecules), dπ-pπ bonds, Bent rule and enegretics of hybridization, some simple reactions of covalently bonded molecules Metal-Ligand Bonding: Limitation of crystal field theory, molecular orbital theory, octahedral, tetrahedral and square planar complexes, π-bonding and molecular orbital theory.


UNIT-II
Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their
interaction, trends in stepwise constants, factors affecting the stability of metal complexes with reference to the nature of metal ion and ligand, chelate effect and its thermodynamic origin, determination of binary formation constants by pH-metry and spectrophotometry


UNIT-III
Reaction Mechanism of Transition Metal Complexes: Energy profile of a reaction, reactivity
of metal complexes, inert and labile complexes, kinetic application of valence bond and crystal field theories, kinetics of octahedral substitution, acid hydrolysis, factors affecting acid hydrolysis, base hydrolysis, conjugate base mechanism, direct and indirect evidences in favor of conjugate mechanism, anation reactions, reactions without metal ligand bond cleavage


UNIT-IV
Substitution reactions in square planar complexes, the trans effect, mechanism of the substitution reaction. Redox reactions, electron transfer reactions, mechanism of the subtitution reaction, Redox reactions, electron transfer reactions, mechanism of one electron transfer reactions, outer sphere type reactions, cross reactions and Marcus-Hush theory, inner sphere type reactions.


UNIT-V
Electronic Spectra and Magnetic Properties of Transition Metal Complexes: Spectroscopic
ground states, correlation, Orgel and Tanabe-Sugano diagrams for transition metal complexes
(d1-d9 states), Calculations of Dq, B and â parameters, charge transfer spectra, spectroscopic
method of assignment of absolute configuration in optically active metal chelates and their
stereochemical information, anomalous magnetic moments, magnetic exchange coupling and
spin crossover.

Books Recommended:
1. Advanced Inorganic Chemistry, F.A.Cotton and Wilkinson, John Wiley
2. Inorganic Chemistry, J.E.Huhey, Harpes & Row
3. Chemistry of the Elements, N.N. Greenwood and A. Earnshow, Pergamon.
4. Inorganic Electronic Spectroscopy, ABP Lever, Elseview
5. Magnetochemistry, R.L. Carlin, Springer Verlag


Syllabus for M.Sc. Chemistry (CBCS) MLSU (Mohanlal Sukhadia University), Udaipur

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