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  #1  
June 23rd, 2016, 09:55 AM
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PVC HCL Emission

Please provide me the information about the Experimental and mechanism analyses on HCL emission control during PVC combustion in fixed beds?
  #2  
June 23rd, 2016, 10:34 AM
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Join Date: Mar 2012
Re: PVC HCL Emission

Incineration of chlorinated plastic (PVC) in strong squanders contributes much to HCL contamination in air environment. The qualities of HCL emanations and diminishment amid PVC ignition were directed in an about isothermal, remotely warmed, level quartz-tube reactor. With expanding temperature from 700 to 900 degrees C, the transformation of HCL expanded indulgently from 82.5% to 88.3%.

This is a research centre study on the diminishment of hydrochloric corrosive (HCL) emanations from the ignition of poly(vinyl chloride) (PVC), by in-heater infusion of calcium-and magnesium-based sorbents.

Tests were directed in an about isothermal, electrically warmed, drop-tube heater, at gas temperatures of 850 and 1050 degrees C. PVC and the sorbents were premixed in powder frame and infused in the heater, where burning of the fuel, arrival of HCl, and chlorination of the sorbents occurred.

Burning was all around fuel-incline, with mass proportionality proportions in the scope of 0.2-0.5; molecule warming rates were 10(4)- 10(5) K/sec; gas living arrangement times were inexact to 1 sec. Tests smoldered unadulterated pummeled PVC (to serve as a gauge) or PVC blended with pounded Ca(OH)(2), Mg(OH)(2), calcium acetic acid derivation (CA), magnesium acetic acid derivation (MA), calcium-magnesium acetic acid derivation (CMA), calcium formate (CF), calcium propionate (CP), and calcium benzoate (CB).

The molecule size of PVC was in the scope of 125-150 mu m, the span of the sorbents differed however it was normally <100 mu m. The Ca/Cl or Mg/Cl molar proportions were set to 1:2, mirroring a stoichiometric arrangement, aside from CMA where the Ca/Cl proportion was set to either 1:6 or 1:3.

The HCl decrease productivity of the sorbents in these runs ran from 3% to 98%. The calcium-based sorbents displayed high HCl catch efficiencies (72-98%), particularly the natural salts (89-98%).

The last, endless supply of their natural segments, framed high-porosity cenospheric particles, which forced negligible mass dispersion impediments. The magnesium-based sorbents did not respond fundamentally (3-5%) with HCl in this temperature range.

Nonetheless, an extensive portion of the magnesium in CMA seems to have partaken in the chlorination response. Shifting the gas temperature between 850 degrees C and 1050 degrees C did not fundamentally influence the HCl catch proficiency of the sorbents.


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